A Multi-Layer Model of Carbon Dioxide

I have put together a simple multi-layer model of  carbon dioxide in the troposphere.  It is based upon the same principles as the two-layer model and the three-layer model.  It accounts for the temperature and pressure profiles from the  previous post and it is part of a primer on infrared spectroscopy and global warming.  Just like those other models there are still caveats; this model is intended to be illustrative of concepts and therefore it is conceptually simple.

A Three-Layer Model

This post is part of a primer on infrared spectroscopy and global warming. The previous post introduces a two-layer model  and is a necessary prerequisite to understanding this post.  In this post I start with the following assumptions.  There is a source of infrared radiance that has emissivity of 1, i.e., it radiates as a perfect blackbody at a temperature of  288 K.  The radiance from that layer is I₀

There is a layer of air 1000 m thick with 380 ppm carbon dioxide at a temperature of 278 K.  There is another layer of air 1000 m thick with 380 ppm carbon dioxide at 268 K.  All layers are at a constant pressure of one atmosphere.

A Two-Layer Model

This post is part of a primer on infrared spectroscopy and global warming. The previous post discusses the issue of saturation in the 14-micron band of carbon dioxide in a single-layer model.   The post before that discusses Beer's Law, and is a necessary prerequisite to understanding this post.  This post starts to look beyond the single-layer model, by discussing a two-layer model, and beginning a discussion of radiative transfer.

The Beer-Lambert Law

Introduction 


This post is part of a primer on infrared spectroscopy and global warming. The previous post  looks at the features of the spectra of molecules of interest molecules and radiation and discusses how molecules give rise to infrared spectra.  This post looks at the question of how much radiation is absorbed by gas phase molecules in a laboratory setting and examines some of the differences between the laboratory gas cell and the earth's atmosphere.

A Primer on Infrared Spectroscopy and Global Warming

Introduction

This post and the posts linked to it through section headers together form a primer on infrared spectroscopy and how it relates to global warming.  The purpose of the primer is not be to convince skeptics that global warming is real, but rather to explain some of the terms and issues being discussed in climate science.  My goal is not to write a super technical explanation of infrared spectroscopy.  That's been done so many times that it is hardly worth doing again.

Rather, my intent is to write something that clearly describes infrared spectroscopy and relates it to global warming that tries to explain some fairly technical concepts in reasonably plain language.  As such there is an inevitable loss of fidelity about some of the fine points of infrared spectroscopy.  Anyone interested in such detail can follow some of the sources that I will provide.  At some point one has to compromise between accessibility and technical accuracy.  I hope that the choices made in this primer are helpful to some people trying to understand this topic.  This post is an outline of the topics addressed in the linked entries.

What is Infrared Radiation (IR)?

Figure source

This first post starts with the basics.  It discusses the electromagnetic spectrum and where infrared radiation fits into it.  It discusses waves and their measures.  It introduces the idea of electric dipole radiation.  It discusses the units of radiation wavelength, frequency. It ends by discussing photons and energy quantization.